Hard-sphere radial distribution function again.

نویسندگان

  • Andrij Trokhymchuk
  • Ivo Nezbeda
  • Jan Jirsák
  • Douglas Henderson
چکیده

A theoretically based closed-form analytical equation for the radial distribution function, g(r), of a fluid of hard spheres is presented and used to obtain an accurate analytic representation. The method makes use of an analytic expression for the short- and long-range behaviors of g(r), both obtained from the Percus-Yevick equation, in combination with the thermodynamic consistency constraint. Physical arguments then leave only three parameters in the equation of g(r) that are to be solved numerically, whereas all remaining ones are taken from the analytical solution of the Percus-Yevick equation.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 123 2  شماره 

صفحات  -

تاریخ انتشار 2005